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Langmuir Isotherm Calculator

Find the fractional surface coverage from the Langmuir constant and pressure (or concentration).

 

 

Coverage θ–

About this calculator

Use this calculator in an adsorption lab when you have K from a fit and a gas pressure (or solution concentration) and want θ.

The calculation is θ = Kp / (1 + Kp). K and p must be inverses of each other so that Kp is dimensionless. Coverage runs from 0 to 1 as p goes from 0 to infinity.

This is the single-site Langmuir isotherm. It does not include multilayer BET adsorption, a Freundlich exponent, or site heterogeneity.

K: Langmuir constant K, in 1/pressure or 1/concentration, for example 0.5 kPa⁻¹.

p or c: Pressure or concentration in the matching unit, for example 2 kPa.

Coverage θ: Fraction of surface occupied, between 0 and 1.